Oxidation of aniline and some para-substituted anilines by benzimidazolium fluorochromate in aqueous acetic acid medium – A kinetic and mechanistic study
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چکیده
منابع مشابه
MP2 study on the variation of stacking interactions in aniline and some para substituted aniline systems
The use of appropriate level of theories for studying weak van der Waal interactions such as 8-8stacking interactions of aromatic molecules has been an important aspect, since the high levelmethods have limitations for application to large molecules. The differences in the stacking energiesof various aromatic molecular structures are found significant. It is also very important for identifyingt...
متن کاملTripropylammonium Fluorochromate Oxidation of 2-Methyl-1-Propanol In Acid Medium: A Kinetic Study
1 P.G Dept. of Chemistry, Sir Sayyed College, Aurangabad, 431001, India. 2 Raje Shivaji College, Bajaj nagar, Waluj, Aurangabad, 431001, India. __________________________________________________________________________________________ Abstract: The Kinetics of oxidation of 2-methyl-1-propanol by tripropylammonium fluorochromate {TPAFC} has been studied Spectrophotometrically catalyzed by Sulphu...
متن کاملCyclic potential sweep electro polymerization of aniline and substituted aniline in acidic medium: A kinetic study
The cyclic potential sweep (CPS) was applied to aniline and substituted aniline to study the kinetic aspects and mechanism of polymerization of anilines, the dependence of the deposition rate of aromatic amines (i.e., deposition charge on number of cycles, scan rate and concentration of monomer). In this method, the mass of polymer deposited at electrode is a function of anodic peak current tha...
متن کاملmp2 study on the variation of stacking interactions in aniline and some para substituted aniline systems
the use of appropriate level of theories for studying weak van der waal interactions such as 8-8stacking interactions of aromatic molecules has been an important aspect, since the high levelmethods have limitations for application to large molecules. the differences in the stacking energiesof various aromatic molecular structures are found significant. it is also very important for identifyingt...
متن کاملChromic Acid Oxidation of Methylaminopyrazole Formamidine in Sulfuric Acid Medium: A Kinetic and Mechanistic Approach
The kinetics of chromic acid oxidation of one of aminopyrazole formamidine derivatives, namely N,N-dimethylN’-(5-methyl-1H-pyrazol-3-yl) formamidine (MAPF)in sulfuric acid solutions has been investigated at constant ionic strength and temperature. The progress of the reaction was followed spectrophotometrically. The reaction showed a first order dependence on [chromic acid] and fractional-first...
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ژورنال
عنوان ژورنال: Arabian Journal of Chemistry
سال: 2014
ISSN: 1878-5352
DOI: 10.1016/j.arabjc.2010.10.020